Thermal study of mononuclear Pd(II) complexes of the type [Pd(X)(2)(Rtu)(PPh3)] (X = Cl, SCN; Rtu = N-methylthiourea, N-phenylthiourea)

dc.contributorUniversidade Estadual Paulista (Unesp)
dc.date.accessioned2014-05-20T15:31:11Z
dc.date.accessioned2022-10-05T17:03:20Z
dc.date.available2014-05-20T15:31:11Z
dc.date.available2022-10-05T17:03:20Z
dc.date.created2014-05-20T15:31:11Z
dc.date.issued2011-11-01
dc.identifierJournal of Thermal Analysis and Calorimetry. Dordrecht: Springer, v. 106, n. 2, p. 379-383, 2011.
dc.identifier1388-6150
dc.identifierhttp://hdl.handle.net/11449/40387
dc.identifier10.1007/s10973-010-1228-4
dc.identifierWOS:000296065100012
dc.identifier3300223970814448
dc.identifier8980849254118153
dc.identifier7927677053650819
dc.identifier0000-0002-0057-7964
dc.identifier.urihttp://repositorioslatinoamericanos.uchile.cl/handle/2250/3911378
dc.description.abstractThe synthesis, spectroscopic characterization, and thermal analysis of the compounds [Pd(X)(2)(mtu)(PPh3)] (X = Cl- (1), SCN- (2); mtu = N-methylthiourea; PPh3 = triphenylphosphine) and [Pd(X)(2)(phtu)(PPh3)] (X = Cl- (3), SCN- (4); phtu = N-phenylthiourea) are described. The thermal decomposition of the compounds occurs in two, three, or four stages and the final decomposition products were identified as Pd-0 by X-ray powder diffraction. The thermal stability order of the complexes is 4 > 3 > 2 > 1.
dc.languageeng
dc.publisherSpringer
dc.relationJournal of Thermal Analysis and Calorimetry
dc.relation2.209
dc.relation0,587
dc.rightsAcesso restrito
dc.sourceWeb of Science
dc.subjectPalladium (II) compounds
dc.subjectThioureas
dc.subjectPseudohalides
dc.subjectThermal analysis
dc.titleThermal study of mononuclear Pd(II) complexes of the type [Pd(X)(2)(Rtu)(PPh3)] (X = Cl, SCN; Rtu = N-methylthiourea, N-phenylthiourea)
dc.typeArtigo


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