Trabalho apresentado em evento
New glasses in the system InF3-BaF2-ErPO4
Fecha
1998-01-01Registro en:
Infrared Glass Optical Fibers and Their Applications. Bellingham: Spie-int Soc Optical Engineering, v. 3416, p. 186-191, 1998.
0277-786X
10.1117/12.323389
WOS:000076793600021
2998503841917815
6446047463034654
Autor
Universidade Estadual Paulista (Unesp)
Resumen
New glasses have been obtained in the system InF3-BaF2-ErPO4. Glass compositions with up to 30% mol Er3+ were shown to exist and characterized by thermal analysis, x-ray: diffraction, IR absorption and electronic spectroscopy. The systems with high Er3+ content were studied recording IR and visible emission spectral characteristics. A specially elaborated technique allowed the preparation of a high purity phosphate precursor ErPO4. X-ray identification of the crystalline phases appearing during thermal treatment have been carried out and parameters of a mixed fluoride Ba4In3-nErnF17 calculated.