dc.contributorUniv Buenos Aires
dc.contributorUniversidade Estadual Paulista (Unesp)
dc.date.accessioned2014-05-20T15:26:56Z
dc.date.accessioned2022-10-05T16:40:21Z
dc.date.available2014-05-20T15:26:56Z
dc.date.available2022-10-05T16:40:21Z
dc.date.created2014-05-20T15:26:56Z
dc.date.issued2003-03-01
dc.identifierPowder Diffraction. Newtown Sq: J C P D S-int Centre Diffraction Data, v. 18, n. 1, p. 50-55, 2003.
dc.identifier0885-7156
dc.identifierhttp://hdl.handle.net/11449/36996
dc.identifier10.1154/1.1538188
dc.identifierWOS:000181517200011
dc.identifierWOS000181517200011.pdf
dc.identifier.urihttp://repositorioslatinoamericanos.uchile.cl/handle/2250/3908607
dc.description.abstractThe capacity of goethite for Cd-II substitution has been explored in a series of synthetic samples prepared from Fe-III and Cd-II nitrate solutions aged 21 days in alkaline media. The total metal content ([ Fe] + [ Cd]) was 0.071 M in all preparations. The samples have been characterized by chemical and X-ray diffraction analysis; the morphology of the solids is described. The cell parameters for all samples were obtained by the Rietveld fits to the X-ray diffraction data. Refined structures show that for samples prepared at the final molar ratio mu(Cd)less than or equal to5.50 (expressed as mu(Cd) = 100X[Cd]/[Cd] + [Fe]), a (Cd, Fe)-goethite is the only crystalline product. In these samples, the unit cell parameters increased as a function of Cd concentration, indicating Cd incorporation in the structural frame. At the preparative ratio, mu(Cd)=7.03, the incorporation of Cd in the goethite structure is drastically reduced and a probable Cd-substituted hematite is formed together with the Fe,Cd-goethite. (C) 2003 International Centre for Diffraction Data.
dc.languageeng
dc.publisherJ C P D S-int Centre Diffraction Data
dc.relationPowder Diffraction
dc.relation0.519
dc.relation0,319
dc.rightsAcesso restrito
dc.sourceWeb of Science
dc.subjectX-ray powder diffraction
dc.subjectRietveld analysis
dc.subjectsubstituted goethite
dc.subjectcadmium
dc.subjectsubstituted hematite
dc.titleStructural study of a series of synthetic goethites obtained in aqueous solutions containing cadmium(II) ions
dc.typeArtigo


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