Synthesis and characterization of a new platinum(II) complex with L-mimosine

Artigo

Fecha

2005-11-10

Registro en:

Journal of Coordination Chemistry. Abingdon: Taylor & Francis Ltd, v. 58, n. 16, p. 1477-1483, 2005.

0095-8972

http://hdl.handle.net/11449/31685

10.1080/00958970500236209

WOS:000233020800010

http://repositorioslatinoamericanos.uchile.cl/handle/2250/3904391

Autor

Universidade Estadual Paulista (Unesp)

Universidade de São Paulo (USP)

Institución

Universidade Paulista Júlio de Mesquita Filho (Brasil)

Resumen

Synthesis and characterization of a new Pt(II)-mimosine complex are described. Elemental, mass spectrometry and thermal analyses for the complex are consistent with the formula [PtCl2(C8H10N2O4)]center dot 1.5H(2)O. C-13 NMR, N-15 NMR and infrared spectroscopy indicate coordination of the ligand to Pt(II) through the N and O atoms in a square-planar geometry. The final residue after thermal treatment was identified as metallic Pt. The complex is soluble in dimethylsulfoxide.

Materias

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