A ONE STEP FUNCTIONALIZATION, COORDINATION OF N3P3Cl6 USING [CpFe(dppe)SC6H4OH]+

dc.creatorDíaz,C
dc.creatorSpodine,E
dc.creatorMoreno,Y
dc.creatorCarrasco,E
dc.date2004-09-01
dc.date.accessioned2017-03-07T15:36:19Z
dc.date.available2017-03-07T15:36:19Z
dc.identifierhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072004000300002
dc.identifier.urihttp://repositorioslatinoamericanos.uchile.cl/handle/2250/387982
dc.descriptionThe new iron-thiolate complex [CpFe(dppe)SC6H4OH]PF6 (1), prepared by the oxidative addition of CpFe(dppe)I (2) to HSC6H4OH (3), reacts in one step with N3P3Cl6 (4) in acetone to give the hexanuclear iron-triolate complex N3P3[CpFe(dppe)SC6 H4O]6 (5), the first cyclotriphosphazene containing thiolate groups coordinated to a metal. Electrochemical data suggest the absence of electronic communication between the iron centers. Magnetic properties for the new complexes are discussed
dc.formattext/html
dc.languageen
dc.publisherSociedad Chilena de Química
dc.sourceJournal of the Chilean Chemical Society v.49 n.3 2004
dc.subjectcyclophosphazenes
dc.subjectiron-thiolates
dc.subjectmagnetic properties
dc.subjectsulphur ligands
dc.titleA ONE STEP FUNCTIONALIZATION, COORDINATION OF N3P3Cl6 USING [CpFe(dppe)SC6H4OH]+
dc.typeArtículos de revistas


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