Artículos de revistas
Broadening the scope of high structural dimensionality nanomaterials using pyridine-based curcuminoids
Fecha
2021Registro en:
Dalton Trans., 2021, 50, 7056
10.1039/d1dt00708d
Autor
Rodríguez Cid, Laura
Qian, Wenjie
Iribarra Araya, Joseline Valentina
Etcheverry Berríos, Álvaro
Martínez Olmos, Eulalia
Choquesillo Lazarte, Duane
Sañudo, Eva Carolina
Roubeau, Olivier
López Periago, Ana María
González Campo, Arántzazu
Planas, José G.
Soler Jauma, Monica
Domingo Maroto, Concepcion
Aliaga Alcalde, Núria
Institución
Resumen
We present a new heteroditopic ligand (3pyCCMoid) that contains the typical skeleton of a curcuminoid
(CCMoid) decorated with two 3-pyridyl groups. The coordination of 3pyCCMoid with ZnII centres results
in a set of novel coordination polymers (CPs) that display different architectures and dimensionalities
(from 1D to 3D). Our work analyses how synthetic methods and slight changes in the reaction conditions
affect the formation of the final materials. Great efforts have been devoted toward understanding the
coordination entities that provide high dimensional systems, with emphasis on the characterization of 2D
materials, including analyses of different types of substrates, stability and exfoliation in water. Here, we
foresee the great use of CCMoids in the field of CPs and emphasize 3pyCCMoid as a new-born linker.