dc.creator | Bonesi, Alejandro Roberto | |
dc.creator | Triaca, Walter Enrique | |
dc.creator | Castro Luna Berenguer, Ana María del Carmen | |
dc.date | 2009 | |
dc.date | 2019-10-04T14:38:36Z | |
dc.identifier | http://sedici.unlp.edu.ar/handle/10915/82718 | |
dc.identifier | issn:0872-1904 | |
dc.description | Carbon-supported binary PtSn/C and ternary PtSnNi/C catalysts were prepared for the electro-oxidation of ethanol. The carbon-supported nanoparticles were synthesised by employing a modified polyol methodology and characterised in terms of structure, morphology and composition by using XRD, EDX and TEM techniques. Their electrocatalytic behaviour for ethanol oxidation (EO) was investigated by employing a disccomposite electrode covered by a thin layer of catalyst imbedded in a Nafion polymer electrolyte film. An enhancement of the EO through a negative shift of the onset oxidation potential and higher current density at constant potentials were observed on the PtSnNi/C electrodes as compared to those for PtSn/C electrodes. The temperature was changed in the range 40 °C ≤ t ≤ 80 °C, and the variation of the activation energy calculated by linear regression of the Arrhenius plots. | |
dc.description | Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas | |
dc.format | application/pdf | |
dc.format | 193-201 | |
dc.language | en | |
dc.rights | http://creativecommons.org/licenses/by-nc-sa/4.0/ | |
dc.rights | Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0) | |
dc.subject | Química | |
dc.subject | Catalyst | |
dc.subject | Ethanol | |
dc.subject | Nickel | |
dc.subject | Platinum | |
dc.subject | Polyol | |
dc.subject | Tin | |
dc.title | Nanocatalysts for ethanol oxidation: Synthesis and characterisation | |
dc.type | Articulo | |
dc.type | Articulo | |