dc.contributor | Zeni, Gilson Rogério | |
dc.contributor | http://lattes.cnpq.br/2355575631197937 | |
dc.contributor | Azeredo, Juliano Braun de | |
dc.contributor | http://lattes.cnpq.br/6704567679943812 | |
dc.contributor | Campos, Patrick Teixeira | |
dc.contributor | http://lattes.cnpq.br/9549998755426589 | |
dc.creator | Prochnow, Thaís | |
dc.date.accessioned | 2017-05-25 | |
dc.date.available | 2017-05-25 | |
dc.date.created | 2017-05-25 | |
dc.date.issued | 2016-02-29 | |
dc.identifier | PROCHNOW, Thaís. Intramolecular cyclization of 1-benzyl-2-alkylbenzene promoted by FeCl3 and diorganyl of dichalcogenide: synthesis of 9-(organochalcogen)-5H-benzo[7]annulenes. 2016. 112 f. Dissertação (Mestrado em Química) - Universidade Federal de Santa Maria, Santa Maria, 2016. | |
dc.identifier | http://repositorio.ufsm.br/handle/1/10614 | |
dc.description.abstract | In the present work, a series of 1-benzyl-2-alkylbenzenes functionalized was subjected to intramolecular cyclization reaction promoted by iron(III) chloride with diorganyl dichalcogenide allowed the synthesis of 9-(organochalcogen)-5H-benzo[7]annulenes whereas the mutual action between diorganyl dichalcogenide and iron(III) chloride in a 0.5:1.0 mole ratio was essential in order to achieve the maximal yields of the products. The cyclization reaction tolerated a variety of functional groups, such as trifluoromethyl, chloro, fluorine and methoxyl, in both 1-benzyl-2-alkynylbenzenes and diorganyl diselenides, giving the seven-membered carbocyclic exclusively via a 7-endo-dig cyclization process, it resulted in a total of 23 samples in 45-77 % yield. | |
dc.publisher | Universidade Federal de Santa Maria | |
dc.publisher | BR | |
dc.publisher | Química | |
dc.publisher | UFSM | |
dc.publisher | Programa de Pós-Graduação em Química | |
dc.rights | Acesso Aberto | |
dc.subject | Carbociclização | |
dc.subject | Dicalcogeneto de diorganoíla | |
dc.subject | Alquínos | |
dc.subject | Carbocyclic | |
dc.subject | Diorganyl dichalcogenide | |
dc.subject | Alkines | |
dc.title | Ciclização intramolecular do 1-benzil-2-alquinilbenzeno promovida por FeCl3 e dicalcogeneto de diorganoíla: síntese dos 9-(organocalcogênio)-5H-benzo[7]anulenos | |
dc.type | Dissertação | |