Artículos de revistas
Tetradentate schiff base copper(II) complexes
Fecha
1999-12-01Registro en:
Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, v. 29, n. 2, p. 171-192, 1999.
0094-5714
10.1080/00945719909349442
WOS:000078852500001
2-s2.0-0033482759
Autor
Universidade Estadual Paulista (Unesp)
Universidade Federal de São Carlos (UFSCar)
Institución
Resumen
Ten copper(II) complexes of tetradentate Schiff bases obtained by condensing two moles of an o-hydroxyphenylcarbonyl compound with a diamine have been prepared and characterized by elemental analyses, melting points, IR and electronic spectra. The IR and electronic spectra of the free ligand and the complexes are compared and discussed. The deconvolution of the visible spectra of the complexes in CHCl3, approximately C2v or C1, yielded four peaks at ca. 15000, 17000, 18000-19000, and 20000-22000 cm-1, assigned to the four d-d transitions.