Thermal behavior of copper(II) pseudohalide complexes containing bidentate amines

dc.contributorUniversidade Estadual Paulista (Unesp)
dc.contributorUniversidade de São Paulo (USP)
dc.date.accessioned2014-05-20T15:19:57Z
dc.date.available2014-05-20T15:19:57Z
dc.date.created2014-05-20T15:19:57Z
dc.date.issued2002-08-01
dc.identifierJournal of Thermal Analysis and Calorimetry. Dordrecht: Kluwer Academic Publ, v. 69, n. 2, p. 455-464, 2002.
dc.identifier1418-2874
dc.identifierhttp://hdl.handle.net/11449/31330
dc.identifier10.1023/A:1019947420249
dc.identifierWOS:000177723200007
dc.description.abstractPseudohalide complexes of copper(II) with aliphatic bidentate amines, [Cu(N-3)(2)(N,N-diEten)](2) 1, [Cu(NCO)(2)(N,N-diEten)](2) 2, [Cu(NCO)(2)(N,N-diMeen)](2) 3, [Cu(N-3)(NCS)(N,N'-diMeen)](2) 4 and [Cu(N-3)(NCO)(N,N-diMeen)](2) 5 (N,N-diEten=N,N-diethylethylenediamine; N,N-diMeen=N,N- dimethyl-ethylenediamine and N,N'-diMeen = N,N'-dimethylethylenediamine), were prepared, characterized and their thermal behavior was investigated by TG curves. According to thermal analysis and X-ray diffraction patterns all compounds decomposed giving copper(II) oxide as final product. The mechanisms of decomposition were proposed and an order of thermal stability was established.
dc.languageeng
dc.publisherKluwer Academic Publ
dc.relationJournal of Thermal Analysis and Calorimetry
dc.rightsAcesso restrito
dc.sourceWeb of Science
dc.subjectbidentate amines
dc.subjectcopper
dc.subjectinfrared spectroscopy
dc.subjectpseudohalide
dc.subjectsynthesis
dc.subjectthermal analysis
dc.titleThermal behavior of copper(II) pseudohalide complexes containing bidentate amines
dc.typeArtículos de revistas


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