Artículos de revistas
Synthesis, spectral and thermal studies on dicarboxylate-bridged palladium(II) coordination polymers. Part II
Fecha
2009-07-01Registro en:
Journal of Thermal Analysis and Calorimetry. Dordrecht: Springer, v. 97, n. 1, p. 153-156, 2009.
1388-6150
10.1007/s10973-009-0249-3
WOS:000270840800027
7927677053650819
0000-0002-0057-7964
Autor
Universidade Estadual Paulista (Unesp)
Universidade de São Paulo (USP)
Institución
Resumen
The synthesis and thermal behavior of the new [Pd(fum)(bipy)] (n) center dot 2nH(2)O (1), [Pd(fum)(bpe)] (n) center dot nH(2)O (2) and [Pd(fum)(pz)] (n) center dot 3nH(2)O (3) {bipy = 4,4'-bipyridine, bpe = 1,2-bis(4-pyridyl)ethene and pz = pyrazine} fumarate complexes are described in this work as well their characterization by IR and (13)C CPMAS NMR spectroscopies. TG curves showed that the compounds released organic ligands and lattice water molecules in the temperature range of 46-491 A degrees C. In all the cases, metallic palladium was identified as the final residue.