Artículos de revistas
A new hybrid organic-inorganic chain: [(Phen)Cu-μ-(κ2 O:O′-VP2O10H3)2-Cu(phen)] n
Fecha
2012Registro en:
Acta Crystallographica Section C: Crystal Structure Communications, Volumen 68, Issue 7, 2012, M200-M202.
01082701
16005759
10.1107/S0108270112026005
Autor
Venegas Yazigi, Diego
Vega, Andrés
Valdes de la Barra, Karen
Saldías, Marianela
Le Fur, Eric
Institución
Resumen
The structure of the title compound, poly[(dihydrogenphosphato-?O)(mu 3-hydrogenphosphato)di-mu-oxido-(1,10-phenanthroline)copper(II)vanadium(V)], [CuV(HPO4)(H2PO4)O2(C12H8N2)]n, is defined by [(phen)Cu mu-(?2O:O'-VP2O10H3)2Cu(phen)] units (phen is 1,10-phenanthroline), which are connected to neighbouring units through vanadyl bridges. Neighbouring chains have no covalent bonds between them, although they interdigitate through the phen groups viapp interactions.