Coordinating properties of some solvents in Cr(CO)5L complexes

dc.creatorDiaz, Eloisa
dc.creatorYutronic Sáez, Nicolás
dc.date.accessioned2018-12-20T14:35:59Z
dc.date.available2018-12-20T14:35:59Z
dc.date.created2018-12-20T14:35:59Z
dc.date.issued1988
dc.identifierPolyhedron, Volumen 7, Issue 9, 2018, Pages 673-677
dc.identifier02775387
dc.identifier10.1016/S0277-5387(88)80036-6
dc.identifierhttp://repositorio.uchile.cl/handle/2250/156644
dc.description.abstractThe influence of the donor-acceptor properties of several solvents on the Cr(CO)5 group in the solid [Cr(CO)5·solvent] complexes has been examined by spectroscopic methods. Relationships were found between the acceptor number of solvent with the π acceptor ability (Graham π parameter) and with the λmax for the ligand field 1A1 → 1E transition, in the carbonyl chromium complexes. These relations are discussed in terms of the dative metal-ligand π bonding. From these results, it is possible to demonstrate the π contribution in the acceptor number. © 1988 Pergamon Press plc.
dc.languageen
dc.rightshttp://creativecommons.org/licenses/by-nc-nd/3.0/cl/
dc.rightsAttribution-NonCommercial-NoDerivs 3.0 Chile
dc.sourcePolyhedron
dc.subjectPhysical and Theoretical Chemistry
dc.subjectInorganic Chemistry
dc.subjectMaterials Chemistry
dc.titleCoordinating properties of some solvents in Cr(CO)5L complexes
dc.typeArtículos de revistas


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