Oxidation of mesoionic oxazolones by oxygen

dc.creatorRodriguez, H.
dc.creatorMarquez, A.
dc.creatorChuaqui, C. A.
dc.creatorGomez, B.
dc.date.accessioned2018-12-20T14:06:20Z
dc.date.available2018-12-20T14:06:20Z
dc.date.created2018-12-20T14:06:20Z
dc.date.issued1991
dc.identifierTetrahedron, Volumen 47, Issue 30, 2018, Pages 5681-5688
dc.identifier00404020
dc.identifier10.1016/S0040-4020(01)86521-2
dc.identifierhttps://repositorio.uchile.cl/handle/2250/153912
dc.description.abstractThe reaction of molecular oxygen with several 2,4-disubstituted oxazolones (3a-3g) is studied in the present paper. It is shown that oxygen may induce oxidative dimerization to dehydrodimers (7a-7g) via the mesoionic form of the oxazolone. The equilibriation between the ketonic and the mesoionic forms. It is demonstrated that this equilibrium and the dimerization process are dependent on the properties of the solvent and the type of substitution in the oxazolones. © 1991.
dc.languageen
dc.rightshttp://creativecommons.org/licenses/by-nc-nd/3.0/cl/
dc.rightsAttribution-NonCommercial-NoDerivs 3.0 Chile
dc.sourceTetrahedron
dc.subjectBiochemistry
dc.subjectDrug Discovery
dc.subjectOrganic Chemistry
dc.titleOxidation of mesoionic oxazolones by oxygen
dc.typeArtículo de revista


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