Artículo de revista
Catalyse et inhibition de deux reactions concurrentes en milieu micellaire cationique
Fecha
1981Registro en:
Tetrahedron, Volumen 37, Issue 17, 2018, Pages 2977-2982
00404020
10.1016/S0040-4020(01)98910-0
Autor
Soto, R.
Meyer, G.
Viout, P.
Institución
Resumen
The general acid catalysed hydrolysis and the intramolecular nucleophilic anionic cyclization of acyloximes operate concurrently in water at pH 7-9. Hydrolysis is inhibited by cationic micelles; changing the length of the acyl chain does not affect the micellar effect, possibly because the environment of the reacting species is not influenced by this variation in the structure of the micelle. © 1981.