INTRAMOLECULAR [4+2] DIELS-ALDER CYCLOADDITIONS OF 2-SUBSTITUTED PHOSPHABENZENE AND ARSABENZENE IN TRIOSMIUM CLUSTERS

dc.creatorArce, A. J.
dc.creatorDeeming, A. J.
dc.creatorDeSanctis, Y.
dc.creatorGarcía, A. M.
dc.creatorManzur Saffie, Jorge
dc.creatorSpodine Spiridonova, Evgenia
dc.date.accessioned2010-09-21T20:02:50Z
dc.date.accessioned2019-04-25T23:29:44Z
dc.date.available2010-09-21T20:02:50Z
dc.date.available2019-04-25T23:29:44Z
dc.date.created2010-09-21T20:02:50Z
dc.date.issued1994-09
dc.identifierORGANOMETALLICS 13(9): 3381-3383
dc.identifier0276-7333
dc.identifierhttp://repositorio.uchile.cl/handle/2250/121046
dc.identifier.urihttp://repositorioslatinoamericanos.uchile.cl/handle/2250/2425400
dc.description.abstract2-(Trimethylsilyl)-1-phosphabenzene and -1-arsabenzene, Me(3)SiC(5)H(4)E (E = P, AS), react with [Os3H2(CO)(10)] to give the clusters [Os3H2(Me(3)SiC(5)H(4)E)(CO)(9)], which contain sigma-bonded, four-electron-donating mu 3-heterocyclic ligands, and the products [Os3H{(Me(3)Si)(2)C(10)H(9)E(2)}(CO)(9)], having tricyclic mu(3)-ligands derived from [4 + 2] Diels-Alder cycloadditions.
dc.languageen
dc.publisherAmer. Chem. Soc.
dc.subjectCOMPLEXES
dc.titleINTRAMOLECULAR [4+2] DIELS-ALDER CYCLOADDITIONS OF 2-SUBSTITUTED PHOSPHABENZENE AND ARSABENZENE IN TRIOSMIUM CLUSTERS
dc.typeArtículos de revistas


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