dc.creatorDonoso Tauda, Oscar
dc.creatorEscobar, Carlos A.
dc.creatorAraya Maturana, Ramiro
dc.creatorVega, Andrés
dc.date.accessioned2009-03-30T16:40:34Z
dc.date.available2009-03-30T16:40:34Z
dc.date.created2009-03-30T16:40:34Z
dc.date.issued2006-10
dc.identifierACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS Volume: 62 Pages: O631-O632 Part: Part 10 Published: OCT 2006
dc.identifier0108-2701
dc.identifierhttps://repositorio.uchile.cl/handle/2250/120587
dc.description.abstractThe molecule of the title compound, C19H20O2S, corresponds to a chiral sulfinyldienol with two stereogenic centres, viz. the C atom susbtituted by the hydroxy group and the sulfinyl S atom. The molecule displays a V-shape in the solid state. The dihedral angle defined by the least-squares planes of the aromatic rings is 72.9 (1)degrees. The packing pattern exhibits the following inter-molecular hydrogen bonds: one O-H center dot center dot center dot O [H center dot center dot center dot O = 1.98 angstrom, O center dot center dot center dot O = 2.785 (4) angstrom and O-H center dot center dot center dot O = 166 degrees] and two C-H center dot center dot center dot O [H center dot center dot center dot O = 2.58 and 2.60 angstrom, C center dot center dot center dot O = 3.527 (5) and 3.347 (5) angstrom, and C-H center dot center dot center dot O = 164 and 134 degrees]. These define a chain along b.
dc.languageen
dc.publisherBLACKWELL PUBLISHING
dc.subjectCHIRAL AUXILIARIES
dc.title(2S,R-S)-6-Phenyl-1-(p-tolylsulfinyl)-hexa-3(E),5(E)-dien-2-ol
dc.typeArtículo de revista


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