Artículo de revista
Bond Fukui Functions As Descriptor of the Electron Density Reorganization in π Conjugated Systems
Fecha
2011-11-29Registro en:
J. Org. Chem., Vol. 77, p. 90−95, 2012
0022-3263
Autor
González Suárez, M.
Aizman, Arie
Soto Delgado, Jorge
Contreras Ramos, Renato
Institución
Resumen
The bond Fukui function is introduced and tested as a new reactivity index
capable of predicting the evolution of bond breaking and formation processes during an
organic reaction involving π conjugated systems. As an illustration, we examine many cases
where substituted ethylenes and dienes may respond to different reagents to yield
cycloaddition, Michael addition, and other reactions at double bonds.