Catalytic activation of methane using n-pentane as co-reactant over Zn/H-ZSM-11 zeolite

Anunziata, Oscar Alfredo; González Mercado, Griselda Verónica; Pierella, Liliana Beatriz

Artículos de revistas

Fecha

2003-04

Registro en:

Anunziata, Oscar Alfredo; González Mercado, Griselda Verónica; Pierella, Liliana Beatriz; Catalytic activation of methane using n-pentane as co-reactant over Zn/H-ZSM-11 zeolite; Springer; Catalysis Letters; 87; 3-4; 4-2003; 167-171

1011-372X

http://hdl.handle.net/11336/36664

CONICET Digital

CONICET

http://repositorioslatinoamericanos.uchile.cl/handle/2250/1905740

Autor

Anunziata, Oscar Alfredo

González Mercado, Griselda Verónica

Pierella, Liliana Beatriz

Institución

Consejo Nacional de Investigaciones Científicas y Tecnológicas (Argentina)

Resumen

The catalytic conversion of methane (C1) into higher hydrocarbons using n-pentane (n-C5) as co-reactant over Zn/H-ZSM-11 zeolite material was studied. The aromatics yield was very high, achieving values of over 40mol% at 500 °C and w/f=30 g h mol-1 with a C1/(C1 +C5) molar fraction (XC1) = 0.30. Contact time and time-on-stream effects on the product distribution were analyzed in detail in order to obtain information about the evolution of different species. The C1 conversion was as high as 30 mol% without CO x reaction products.

Materias

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