Artículos de revistas
Electropolimerization of Functionalizaed Carbazole End-Capped Dendrimers. Formation of Conductive Films
Fecha
2016-07Registro en:
Mangione, Maria Ines; Spanevello, Rolando Angel; Minudri, Daniela; Heredia, Daniel Alejandro; Fernandez, Luciana Andrea; et al.; Electropolimerization of Functionalizaed Carbazole End-Capped Dendrimers. Formation of Conductive Films; Pergamon-Elsevier Science Ltd; Electrochimica Acta; 207; 7-2016; 143-151
0013-4686
CONICET Digital
CONICET
Autor
Mangione, Maria Ines
Spanevello, Rolando Angel
Minudri, Daniela
Heredia, Daniel Alejandro
Fernandez, Luciana Andrea
Otero, Luis Alberto
Fungo, Fernando Gabriel
Resumen
A series of peripherally carbazole functionalized dendrimeric starburst monomers were synthesized and characterized. The electrochemical polymerization over Pt and indium tin oxide electrodes of fully π-conjugated dendrimers allows the generation of electro-active polymeric films. Dendrimers were design with and without electroactive central core (triphenylamine) connected to peripherals moieties, which influence the physicochemical characteristics of the electrogenerated polymers. The versatile electropolymerization methodology allows the generation of thin films of hyperbranched macromolecules with good electrical conductivity, reversible electrochemical processes and electrochromic properties.