Artículos de revistas
Efficiency of 4,4-bis(N,N-diethylamino) benzophenone for the polymerization of dimethacrylate resins in thick sections
Fecha
2011-05-02Registro en:
Schroeder, Walter Fabian; Asmussen, Silvana Valeria; Cook, Wayne D.; Vallo, Claudia Ines; Efficiency of 4,4-bis(N,N-diethylamino) benzophenone for the polymerization of dimethacrylate resins in thick sections; Wiley; Polymer International; 60; 9; 2-5-2011; 1362-1369
0959-8103
Autor
Schroeder, Walter Fabian
Asmussen, Silvana Valeria
Cook, Wayne D.
Vallo, Claudia Ines
Resumen
The efficiency of 4,4′-bis(N,N-diethylamino)benzophenone (DEABP) for the polymerization of dimethacrylate monomers in thick sections (1–2 mm) was studied. DEABP (λmax = 365 nm) represents a complete initiating system as it contains both ketone and amine functional groups. During irradiation, DEABP photobleaches at a fast rate causing deeper penetration of light through the underlying layers, but the photoinitiation efficiency (rate of polymerization per photon absorption rate) is relatively poor. As a result, irradiation of methacrylate monomers at 365 nm results in a slow average polymerization rate and a reduced monomer conversion for thick sections due to the light attenuation caused by the high absorptivity of DEABP and photolysis products. These results highlight the inherent interlinking of light attenuation and photobleaching rate in polymerization of thick sections.