Chemoselective and Sequential Palladium-Catalyzed Couplings for the Generation of Stilbene Libraries via Immobilized Substrates

Traficante, Carla Inés; Fagundez, Catherine; Serra, Gloria L.; Mata, Ernesto Gabino; Delpiccolo, Carina Maria Lujan

Artículos de revistas

Fecha

2016-05

Registro en:

Traficante, Carla Inés; Fagundez, Catherine; Serra, Gloria L.; Mata, Ernesto Gabino; Delpiccolo, Carina Maria Lujan; Chemoselective and Sequential Palladium-Catalyzed Couplings for the Generation of Stilbene Libraries via Immobilized Substrates; American Chemical Society; ACS Combinatorial Science; 18; 5; 5-2016; 225-229

2156-8952

http://hdl.handle.net/11336/61031

CONICET Digital

CONICET

http://repositorioslatinoamericanos.uchile.cl/handle/2250/1889394

Autor

Traficante, Carla Inés

Fagundez, Catherine

Serra, Gloria L.

Mata, Ernesto Gabino

Delpiccolo, Carina Maria Lujan

Institución

Consejo Nacional de Investigaciones Científicas y Tecnológicas (Argentina)

Resumen

A versatile palladium-catalyzed tandem synthetic sequence to afford E-stilbenes libraries has been developed. Excellent regio- and stereocontrol have been achieved by means of the sequence of Hiyama and Heck cross-couplings. Undesirable homocoupling byproducts were avoided employing immobilized substrates.

Materias

HECK COUPLING

HIYAMA COUPLING

PALLADIUM CROSS-COUPLING REACTIONS

SOLID-PHASE ORGANIC SYNTHESIS

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