Artículos de revistas
A Smart Latent Catalyst Containing o‑Trifluoroacetamide Functional Benzoxazine: Precursor for Low Temperature Formation of Very High Performance Polybenzoxazole with Low Dielectric Constant and High Thermal Stability
Fecha
2017-08Registro en:
Zhang, Kan; Han, Lu; Froimowicz, Pablo; Ishida, Hatsuo; A Smart Latent Catalyst Containing o‑Trifluoroacetamide Functional Benzoxazine: Precursor for Low Temperature Formation of Very High Performance Polybenzoxazole with Low Dielectric Constant and High Thermal Stability; American Chemical Society; Macromolecules; 50; 17; 8-2017; 6552–6560
0024-9297
CONICET Digital
CONICET
Autor
Zhang, Kan
Han, Lu
Froimowicz, Pablo
Ishida, Hatsuo
Resumen
A novel difunctional benzoxazine with o-trifluoroacetamide functionality has been synthesized via Mannich condensation. The chemical structure of synthesized monomer has also been confirmed by 1H, 13C, and 19F nuclear magnetic resonance (NMR) spectroscopy and Fourier transform infrared (FT-IR) spectroscopy. The ring-opening polymerization of the resin and the subsequent conversion of the freshly generated polybenzoxazine into polybenzoxazole are studied by FT-IR and differential scanning calorimetry (DSC). In addition to the advantage of low polymerization temperature as other reported o-amide benzoxazines, the o-trifluoroacetamide benzoxazine also exhibits an unexpected lower benzoxazole formation temperature. Furthermore, the resulting fluorinated polybenzoxazole derived from the benzoxazine monomer possesses the combined excellent properties of facile synthesis, easy processability, low dielectric constant, high thermal stability, and long shelf life, evidencing its potential applications in microelectronic industries, aerospace, and other high-performance areas.