Liquid chromatography coupled to molecular fluorescence with postcolumn UV sensitization for thimerosal and derivative compounds monitoring in environmental samples

dc.creatorAcosta, Maria Gimena
dc.creatorTorres, Alberto Sabier
dc.creatorKaplan, Marcos Manuel
dc.creatorFernandez, Liliana Patricia
dc.creatorPacheco, Pablo Hugo
dc.creatorGil, Raul Andres
dc.date.accessioned2018-09-21T19:47:40Z
dc.date.accessioned2018-11-06T13:28:30Z
dc.date.available2018-09-21T19:47:40Z
dc.date.available2018-11-06T13:28:30Z
dc.date.created2018-09-21T19:47:40Z
dc.date.issued2016-10
dc.identifierAcosta, Maria Gimena; Torres, Alberto Sabier; Kaplan, Marcos Manuel; Fernandez, Liliana Patricia; Pacheco, Pablo Hugo; et al.; Liquid chromatography coupled to molecular fluorescence with postcolumn UV sensitization for thimerosal and derivative compounds monitoring in environmental samples; Wiley VCH Verlag; Electrophoresis; 37; 19; 10-2016; 2531-2537
dc.identifier0173-0835
dc.identifierhttp://hdl.handle.net/11336/60651
dc.identifierCONICET Digital
dc.identifierCONICET
dc.identifier.urihttp://repositorioslatinoamericanos.uchile.cl/handle/2250/1875772
dc.description.abstractA HPLC coupled with molecular fluorescence (MF) spectrometry method for determination of thimerosal (THM, sodium ethylmercurythiosalicylate, C9H9HgNaO2S), and derivatives is proposed. A sensitization of MF was provoked by UV irradiation of analytes in a home-made photoreactor that served as interface between the LC column and MF spectrometer. This method is applied to determination of THM, ethyl mercury, and thiosalicylic acid in samples of pharmaceutical industry effluents, and waters of La Carolina and Jáchal rivers situated in the center-west side of San Luis city and in the east of San Juan city (Middle West, Argentine) where the effluents are dumped. The LODs calculated on basis of 3σ criterion were 1.8, 5, and 0.05 μmol/L for THM, ethyl mercury, and for thiosalicylic acid, respectively.
dc.languageeng
dc.publisherWiley VCH Verlag
dc.relationinfo:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1002/elps.201600147
dc.relationinfo:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/abs/10.1002/elps.201600147
dc.rightshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.rightsinfo:eu-repo/semantics/openAccess
dc.subjectCONTAMINATED RIVER WATERS
dc.subjectHPLC-UV-POSTCOLUMN PHOTOCHEMICAL SENSITIZATION
dc.subjectMOLECULAR FLUORESCENCE
dc.subjectPHARMACEUTIC INDUSTRY EFFLUENTS
dc.subjectTHIMEROSAL
dc.titleLiquid chromatography coupled to molecular fluorescence with postcolumn UV sensitization for thimerosal and derivative compounds monitoring in environmental samples
dc.typeArtículos de revistas
dc.typeArtículos de revistas
dc.typeArtículos de revistas


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