dc.creator | Lazzarotto, Márcio | |
dc.creator | Ferreira, Creusa Iara | |
dc.creator | Castellano, Eduardo Ernesto | |
dc.creator | Veglia, Alicia Viviana | |
dc.date.accessioned | 2017-12-22T14:12:35Z | |
dc.date.accessioned | 2018-11-06T12:44:58Z | |
dc.date.available | 2017-12-22T14:12:35Z | |
dc.date.available | 2018-11-06T12:44:58Z | |
dc.date.created | 2017-12-22T14:12:35Z | |
dc.date.issued | 2014-03 | |
dc.identifier | Veglia, Alicia Viviana; Castellano, Eduardo Ernesto; Ferreira, Creusa Iara; Lazzarotto, Márcio; Highly constrained guests in complexes ofp-tert-butylcalix[6]arenedianion: Pentane-1,5-diammonium and choline; Elsevier Science; Journal of Molecular Structure; 1067; 3-2014; 88-93 | |
dc.identifier | 0022-2860 | |
dc.identifier | http://hdl.handle.net/11336/31359 | |
dc.identifier | CONICET Digital | |
dc.identifier | CONICET | |
dc.identifier.uri | http://repositorioslatinoamericanos.uchile.cl/handle/2250/1869764 | |
dc.description.abstract | The structures of the complexes of choline and pentane-1,5-diammonium withp-t-bu-calix[6]arenedianion were determined. Both salts display the calixarene moiety at 1,2,3-alternate conformation, withtwo concave surfaces formed by three aromatic rings, and the phenolate units are at distal positions,interacting with two phenol units by hydrogen bonds.The salt of pentane-1,5-diammonium shows the diammonium connecting both calixarene dianionunits, and one NH3+is locatedendo-calix position and the other occupies anexo-calix position. Thet-butylgroups and the calix cavity constrains the pentane-1,5-diammonium chain to nearsyn-eclipsedandgaucheconformations. The other semi-calix accomodates a THF solvent molecule. The salt of cholineshows the trimethylammonium groups of choline units immersed in these concave surfaces, with severalinteractions N+–C–H—pinteractions with the aromatic semi-cavities | |
dc.language | eng | |
dc.publisher | Elsevier Science | |
dc.relation | info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1016/j.molstruc.2014.03.004 | |
dc.relation | info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0022286014002701 | |
dc.rights | https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ | |
dc.rights | info:eu-repo/semantics/restrictedAccess | |
dc.subject | CALIXARENE | |
dc.subject | CADAVERINE | |
dc.subject | CHOLINE | |
dc.subject | AMMONIUM SALTS | |
dc.subject | X-RAY | |
dc.subject | SUPRAMOLECULAR CHEMISTRY | |
dc.title | Highly constrained guests in complexes ofp-tert-butylcalix[6]arenedianion: Pentane-1,5-diammonium and choline | |
dc.type | Artículos de revistas | |
dc.type | Artículos de revistas | |
dc.type | Artículos de revistas | |