dc.creator | Blanco, Maria Belen | |
dc.creator | Barnes, Ian | |
dc.creator | Wiesen, Peter | |
dc.creator | Teruel, Mariano Andres | |
dc.date.accessioned | 2018-06-05T19:53:55Z | |
dc.date.accessioned | 2018-11-06T11:49:22Z | |
dc.date.available | 2018-06-05T19:53:55Z | |
dc.date.available | 2018-11-06T11:49:22Z | |
dc.date.created | 2018-06-05T19:53:55Z | |
dc.date.issued | 2015-10-01 | |
dc.identifier | Blanco, Maria Belen; Barnes, Ian; Wiesen, Peter; Teruel, Mariano Andres; Kinetics of the reactions of Cl atoms with CF3C(O)OCH3, CF3C(O)OCH2CH3, CF2HC(O)OCH3 in the temperature range of 287-313K and 1 atm; Elsevier Science; Chemical Physics Letters; 638; 1-10-2015; 15-20 | |
dc.identifier | 0009-2614 | |
dc.identifier | http://hdl.handle.net/11336/47379 | |
dc.identifier | CONICET Digital | |
dc.identifier | CONICET | |
dc.identifier.uri | http://repositorioslatinoamericanos.uchile.cl/handle/2250/1859873 | |
dc.description.abstract | Rate coefficients of the reactions of Cl atoms with CF3C(O)OCH3 (k1), CF3C(O)OCH2CH3 (k2) and CF2HC(O)OCH3 (k3) have been measured for the first time in the temperature range of 287–313 K and 1 atm. Temperature dependencies of k are described by the Arrhenius expressions: k1 = (5 ± 2) × 10−12 exp[−(1216 ± 72)/T] (cm3 molecule−1 s−1), k2 = (539 ± 164) × 10−12 exp[−(1637 ± 94)/T] (cm3 molecule−1 s−1) and k3 = (20 ± 9) × 10−12 exp[−(1368 ± 82)/T] (cm3 molecule−1 s−1). The kinetic data are compared with previous theoretical calculations and a correlation between kCl and EHOMO of the halogenated VOC is presented. | |
dc.language | eng | |
dc.publisher | Elsevier Science | |
dc.relation | info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0009261415005989 | |
dc.relation | info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1016/j.cplett.2015.08.011 | |
dc.rights | https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ | |
dc.rights | info:eu-repo/semantics/restrictedAccess | |
dc.subject | FLUOROESTER | |
dc.subject | ARRHENIUS PARAMETERS | |
dc.subject | FTIR | |
dc.title | Kinetics of the reactions of Cl atoms with CF3C(O)OCH3, CF3C(O)OCH2CH3, CF2HC(O)OCH3 in the temperature range of 287-313K and 1 atm | |
dc.type | Artículos de revistas | |
dc.type | Artículos de revistas | |
dc.type | Artículos de revistas | |