info:eu-repo/semantics/article
Experimental and DFT study on the indiummediated synthesis of benzophenones via arylstannanes
Fecha
2014-09Registro en:
Lo Fiego, Marcos Jacinto; Dorn, Viviana B.; Badajoz, Mercedes A.; Lockhart, Maria T.; Chopa, Alicia B.; Experimental and DFT study on the indiummediated synthesis of benzophenones via arylstannanes; Royal Society of Chemistry; RSC Advances; 4; 90; 9-2014; 49079-49085
2046-2069
Autor
Lo Fiego, Marcos Jacinto
Dorn, Viviana B.
Badajoz, Mercedes A.
Lockhart, Maria T.
Chopa, Alicia B.
Resumen
Experimental results of the solvent-free, indium-promoted reaction of aroyl chlorides with arylstannanes showed a narrow scope; its efficiency depends both on the extent of methylation in the latter and on the nature, number and position of the substituents in the former. With the purpose of explaining experimental results, a theoretical analysis with DFT methods was performed for a set of selected cases.