Artículos de revistas
Binding of molecular magnesium hydrides to a zirconocene-enyne template
Fecha
2012-08Registro en:
Angewandte Chemie International Edition,Weinheim : Wiley-VCH Verlag,v. 51, n. 35, p. 8846-8849, Aug. 2012
1433-7851
10.1002/anie.201203372
Autor
Bender, Georg
Wiegand, Thomas
Eckert, Hellmut
Fröhlich, Roland
Daniliuc, Constantin G.
Mück-Lichtenfeld, Christian
Ndambuki, Sylvester
Ziegler, Tom
Kehr, Gerald
Erker, Gerhard
Institución
Resumen
An enyne-zirconium complex stabilizes molecular magnesium hydride ('MG''H IND. 2') and even a molecular hydride, n'C IND. 4''H IND. 9''MG'H. These systems feature magnesium olefin "pi" complexation.