Artículos de revistas
The chemiluminescent peroxyoxalate system: state of the art almost 50 years from its discovery
Fecha
2012Registro en:
ARKIVOC, GAINESVILLE, n. 3, pp. 391-430, FEB, 2012
1551-7004
10.3998/ark.5550190.0013.328
Autor
Ciscato, Luiz Francisco M. L.
Augusto, Felipe A.
Weiss, Dieter
Bartoloni, Fernando H.
Albrecht, Steffen
Brandl, Herbert
Zimmermann, Thomas
Baader, Wilhelm J.
Institución
Resumen
Almost fifty years after the discovery of the peroxyoxalate reaction by E. A. Chandross in the early nineteen sixties, this review article intends to give a general overview on mechanistic aspects of this system and to describe the principles of its analytical application. After a short general introduction on the principles of chemiluminescence and the history of peroxyoxalate discovery, mechanistic aspects of high-energy intermediate formation, its structure and its reaction with an activator in the peroxyoxalate system are discussed. Finally, analytical applications of peroxyoxalate chemiluminescence are exemplified using representative recent examples, including oxalic acid detection in biological samples.