Artículos de revistas
In situ generation of n-butanethiol and its reaction with electron-deficient olefines
Fecha
2008Registro en:
SYNTHETIC COMMUNICATIONS, v.38, n.5, p.789-795, 2008
0039-7911
10.1080/00397910701820897
Autor
GARIANI, Rogerio A.
SANTOS, Alcindo A. Dos
COMASSETO, Joao V.
Institución
Resumen
n-Butanethiol is generated in situ by sequential addition of n-butyllithium and water to elemental sulfur. The n-butanethiol formed was reacted with electron-deficient olefines to give Michael-type addition products in good yields. The method avoids the manipulation of the bad-smelling n-butanethiol.