dc.creatorVALLE, Eliana Maira Agostini
dc.creatorNASCIMENTO, Fabio Batista do
dc.creatorFERREIRA, Antonio Gilberto
dc.creatorBATISTA, Alzir A.
dc.creatorMONTEIRO, Marcos Cláudio Rodrigues
dc.creatorMACHADO, Sérgio de Paula
dc.creatorELLENA, Javier
dc.creatorCASTELLANO, Eduardo E.
dc.creatorAZEVEDO, Eduardo Ribeiro de
dc.date.accessioned2012-03-26T21:44:47Z
dc.date.accessioned2018-07-04T14:24:30Z
dc.date.available2012-03-26T21:44:47Z
dc.date.available2018-07-04T14:24:30Z
dc.date.created2012-03-26T21:44:47Z
dc.date.issued2008
dc.identifierQuímica Nova, v.31, n.4, p.807-812, 2008
dc.identifier0100-4042
dc.identifierhttp://producao.usp.br/handle/BDPI/11862
dc.identifier10.1590/S0100-40422008000400019
dc.identifierhttp://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422008000400019
dc.identifierhttp://www.scielo.br/pdf/qn/v31n4/a19v31n4.pdf
dc.identifier.urihttp://repositorioslatinoamericanos.uchile.cl/handle/2250/1609652
dc.description.abstractThe [RuCl(bipy)(dppb)(4-pic)]PF6 complex was prepared and fully characterized. The X-ray crystal structure of this complex was determined in order to make an unambiguous distinction between the two possible positions of the 4-methylpyridine ligand (4-pic) in the compound: trans to phosphorus atom or trans to nitrogen atom. The [RuCl(bipy)(dppb)(4-pic)]PF6 complex exhibits an unusual temperature-dependent accidental degeneracy of the 31P chemical shifts in its solution NMR spectrum.
dc.languagepor
dc.publisherSociedade Brasileira de Química
dc.relationQuímica Nova
dc.rightsCopyright Sociedade Brasileira de Química
dc.rightsopenAccess
dc.subjectRuthenium
dc.subjectDiphosphine
dc.subjectNMR
dc.titleSobre uma degenerescência acidental nos deslocamentos químicos de RMN de 31P{¹H} em complexos difosfínicos de rutênio
dc.typeArtículos de revistas


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