dc.creator | VALLE, Eliana Maira Agostini | |
dc.creator | NASCIMENTO, Fabio Batista do | |
dc.creator | FERREIRA, Antonio Gilberto | |
dc.creator | BATISTA, Alzir A. | |
dc.creator | MONTEIRO, Marcos Cláudio Rodrigues | |
dc.creator | MACHADO, Sérgio de Paula | |
dc.creator | ELLENA, Javier | |
dc.creator | CASTELLANO, Eduardo E. | |
dc.creator | AZEVEDO, Eduardo Ribeiro de | |
dc.date.accessioned | 2012-03-26T21:44:47Z | |
dc.date.accessioned | 2018-07-04T14:24:30Z | |
dc.date.available | 2012-03-26T21:44:47Z | |
dc.date.available | 2018-07-04T14:24:30Z | |
dc.date.created | 2012-03-26T21:44:47Z | |
dc.date.issued | 2008 | |
dc.identifier | Química Nova, v.31, n.4, p.807-812, 2008 | |
dc.identifier | 0100-4042 | |
dc.identifier | http://producao.usp.br/handle/BDPI/11862 | |
dc.identifier | 10.1590/S0100-40422008000400019 | |
dc.identifier | http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422008000400019 | |
dc.identifier | http://www.scielo.br/pdf/qn/v31n4/a19v31n4.pdf | |
dc.identifier.uri | http://repositorioslatinoamericanos.uchile.cl/handle/2250/1609652 | |
dc.description.abstract | The [RuCl(bipy)(dppb)(4-pic)]PF6 complex was prepared and fully characterized. The X-ray crystal structure of this complex was determined in order to make an unambiguous distinction between the two possible positions of the 4-methylpyridine ligand (4-pic) in the compound: trans to phosphorus atom or trans to nitrogen atom. The [RuCl(bipy)(dppb)(4-pic)]PF6 complex exhibits an unusual temperature-dependent accidental degeneracy of the 31P chemical shifts in its solution NMR spectrum. | |
dc.language | por | |
dc.publisher | Sociedade Brasileira de Química | |
dc.relation | Química Nova | |
dc.rights | Copyright Sociedade Brasileira de Química | |
dc.rights | openAccess | |
dc.subject | Ruthenium | |
dc.subject | Diphosphine | |
dc.subject | NMR | |
dc.title | Sobre uma degenerescência acidental nos deslocamentos químicos de RMN de 31P{¹H} em complexos difosfínicos de rutênio | |
dc.type | Artículos de revistas | |