Artículos de revistas
Distribution And Sources Of Aliphatic And Polycyclic Aromatic Hydrocarbons In Surface Sediments Of Itajai-acu Estuarine System In Brazil
Registro en:
Journal Of The Brazilian Chemical Society. Soc Brasileira Quimica, v. 28, p. 603 - 614, 2017.
0103-5053
1678-4790
WOS:000396347700011
10.21577/0103-5053.20160205
Autor
Frena
Morgana; Bataglion
Giovana A.; Sandini
Sara S.; Kuroshima
Katia N.; Eberlin
Marcos N.; Madureira
Luiz A. S.
Institución
Resumen
Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq) Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES) Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP) The Itajai-Acu estuarine system, located in southern Brazil, has great economic importance due to the presence of two ports (Itajai and Navegantes). This system is affected by industrial and dredging activities, which can cause the remobilization of pollutants accumulated over time in the sediment. In this context, hydrocarbons were assessed in twelve surface sediment samples. n-Alkane and polycyclic aromatic hydrocarbons (PAH) concentrations were determined by gas chromatography and their sources assessed. Total concentrations ranged between 0.50 +/- 0.04 and 69.70 +/- 3.90 mu g g(-1) dry weight (d.w.)for n-alkanes and from 63.9 +/- 12.1 to 1459.0 +/- 43.5 ng g(-1) d.w. for PAH. Most of the sediment samples presented carbon preference index (CPI) values close to unity, indicating that the area is submitted to petroleum-related sources, mainly close to Itajai harbor, where an intense unresolved complex mixture (UCM) was observed. The presence at all stations of alpha beta-hopane biomarkers also indicated petrogenic input. Based on selected PAH ratios, the sedimentary PAH composition reflects a mixture of both petrogenic and pyrolytic sources. A comparison of the PAH concentrations found in this study with those listed in the sediment quality guidelines (SQGs) indicated that adverse biological effects on the biota are rarely expected. 28 4 603 614 Petroleo Brasileiro S.A. (Petrobras), Conselho Nacional de Desenvolvimento Cientifico e Tecnologico (CNPq) [304209/2013-9] Coordenacao de Aperfeicoamento de Pessoal de Nivel Superior (CAPES) Fundacao de Amparo a Pesquisa do Estado de Sao Paulo (FAPESP) [2012/21395-0] Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq) Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES) Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)