Recent Synthetic Additions To The Visible Light Photoredox Catalysis Toolbox

dc.creatorAngnes
dc.creatorRicardo A.; Li
dc.creatorZhou; Correia
dc.creatorCarlos Roque D.; Hammond
dc.creatorGerald B.
dc.date2015
dc.date2016-06-07T13:22:00Z
dc.date2016-06-07T13:22:00Z
dc.date.accessioned2018-03-29T01:41:43Z
dc.date.available2018-03-29T01:41:43Z
dc.identifier
dc.identifierRecent Synthetic Additions To The Visible Light Photoredox Catalysis Toolbox. Royal Soc Chemistry, v. 13, p. 9152-9167 2015.
dc.identifier1477-0520
dc.identifierWOS:000360115100001
dc.identifier10.1039/c5ob01349f
dc.identifierhttp://pubs.rsc.org/en/content/articlelanding/2015/ob/c5ob01349f#!divAbstract
dc.identifierhttp://repositorio.unicamp.br/jspui/handle/REPOSIP/243158
dc.identifier.urihttp://repositorioslatinoamericanos.uchile.cl/handle/2250/1306856
dc.descriptionThe boom in visible light photoredox catalysis (VLPC) research has demonstrated that this novel synthetic approach is here to stay. VLPC enables reactive radical intermediates to be catalytically generated at ambient temperature, a feat not generally allowed through traditional pyrolysis-or radical initiator-based methodologies. VLPC has vastly extended the range of substrates and reaction schemes that have been traditionally the domain of radical reactions. In this review the photophysics background of VLPC will be briefly discussed, followed by a report on recent inroads of VLPC into decarboxylative couplings and radical C-H functionalization of aromatic compounds. The bulk of the review will be dedicated to advances in synergistic catalysis involving VLPC, namely the combination of photoredox catalysis with organocatalysis, including beta-functionalization of carbonyl groups, functionalization of weak aliphatic C-H bonds, and anti-Markovnikov hydrofunctionalization of alkenes; dual catalysis with gold or with nickel, photoredox catalysis as an oxidation promoter in transition metal catalysis, and acid-catalyzed enantio-selective radical addition to pi systems.
dc.description13
dc.description35
dc.description
dc.description9152
dc.description9167
dc.descriptionFundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)
dc.descriptionU.S. Department of State's Bureau of Education and Cultural Affairs
dc.descriptionGovernment of Brazil
dc.descriptionNational Science Foundation [CHE-1401700]
dc.description
dc.description
dc.description
dc.languageen
dc.publisherROYAL SOC CHEMISTRY
dc.publisher
dc.publisherCAMBRIDGE
dc.relationORGANIC & BIOMOLECULAR CHEMISTRY
dc.rightsaberto
dc.sourceWOS
dc.subjectC-h Functionalization
dc.subjectAerobic Oxidative Cyclization
dc.subjectElectron-deficient Alkenes
dc.subjectTransition-metal Catalysis
dc.subjectTertiary Aliphatic-amines
dc.subjectTransfer Radical-addition
dc.subjectThiol-ene Reactions
dc.subjectDe-novo Synthesis
dc.subjectDehydrogenative-coupling Reaction
dc.subjectBiomolecule-compatible Conditions
dc.titleRecent Synthetic Additions To The Visible Light Photoredox Catalysis Toolbox
dc.typeArtículos de revistas
dc.typeResumo


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