Artículos de revistas
Anti-theft Device Staining On Banknotes Detected By Mass Spectrometry Imaging
Registro en:
Forensic Science International. Elsevier Ireland Ltd, v. 260, p. 22 - 26, 2016.
3790738
10.1016/j.forsciint.2015.09.017
2-s2.0-84954286247
Institución
Resumen
We describe the identification and limits of detection of ink staining by mass spectrometry imaging (MSI), as used in anti-theft devices (ATDs). Such ink staining is applied to banknotes during automated teller machine (ATM) explosions. Desorption electrospray ionization (DESI) coupled with high-resolution and high-accuracy orbitrap mass spectrometry (MS) and a moving stage device were applied to obtain 2D molecular images of the major dyes used for staining, that is, 1-methylaminoanthraquinone (MAAQ), rhodamine B (RB) and rhodamine 6G (R6G). MAAQ could not be detected because of its inefficient desorption by DESI from the banknote cellulose surface. By contrast, ATD staining on banknotes is perceptible by the human naked eye only at concentrations higher than 0.2μgcm-2, whereas both RB and R6G at concentrations 200 times lower (as low as 0.001μgcm-2) could be easily detected and imaged by DESI-MSI, with selective and specific identification of each analyte and their spatial distribution on samples from suspects. This technique is non-destructive, and no sample preparation is required, which ensures sample preservation for further forensic investigations. © 2016. 260
22 26 Hernandes, V.V., Franco, M.F., Santos, J.M., Melendez-Perez, J.J., Morais, D.R., Rocha, W.F.D.C., Characterization of ANFO explosive by high accuracy ESI(±)-FTMS with forensic identification on real samples by EASI(-)-MS (2015) Forensic Sci. Int., 249, pp. 156-164 Almeida, M.R., Correa, D.N., Zacca, J.J., Logrado, L.P.L., Poppi, R.J., Detection of explosives on the surface of banknotes by Raman hyperspectral imaging and independent component analysis (2015) Anal. Chim. Acta, 860, pp. 15-22 Lopez, M., Anti-theft device for automated tell machines which blurs or defaces banknotes - uses indelible dye or ink which is stored under pressure in tank which actuated by single from electrical device Número(s) da patente: US5537938-AOokura, J., Anti-theft device e.g. for automated teller machine, has coloring apparatus that sprays coating material on banknotes stored in cash dispenser when abnormal situation such as vibration or sound is detected by abnormality detector, Número(s) da patente: JP2004227443-ASeiden, H., Removal of dye-pack stains on U.S. currency: a reconstruction (1996) Int. J. Forensic Doc. Exam., 3 Martz, R.M., Reutter, D.J., Lasswell, L.D., A comparison of ionization techniques for gas chromatography/mass spectroscopy analysis of dye and lachrymator residues from exploding bank security devices (1983) J. Forensic Sci., 28, pp. 220-227 Egan, J.M., Rickenbach, M., Mooney, K.E., Palenik, C.S., Golombeck, R., Mueller, K.T., Bank security dye packs: synthesis, isolation, and characterization of chlorinated products of bleached 1-(methylamino)anthraquinone (2006) J. Forensic Sci., 51, pp. 1276-1283 Marise, C., Ross, P., Identification of 1-methylaminoanthraquinone on Australian polymeric bank notes (2011) Forensic Sci. Int., 206, pp. 207-210 Verweij, A.M.A., Lipman, P.J.L., Comparison of mass spectrometric techniques for the analysis of trace amounts of 1-methylaminoanthraquinone, used as smoke dye in exploding money suitcases (1993) J. Chromatogr. A, 653, pp. 359-362 Reilly, C.A., Crouch, D.J., Yost, G.S., Fatah, A.A., Determination of capsaicin, dihydrocapsaicin, and nonivamide in self-defense weapons by liquid chromatography-mass spectrometry and liquid chromatography-tandem mass spectrometry (2001) J. Chromatogr. A, 912, pp. 259-267 Jagerdeo, E., Leibowitz, J.N., Schumacher, L., Henningsen, D.A., LeBeau, M., Analysis of trace amount of bank dye and lachrymators from exploding bank devices by solid-phase microextraction and gas chromatography-mass spectrometry (2006) J. Chromatogr. Sci., 44, pp. 86-90 Schmidt, E.M., Franco, M.F., Cuelbas, C.J., Zacca, J.J., Rocha, W.F.C., Borges, R., Characterization of anti-theft devices directly from the surface of banknotes via easy ambient sonic spray ionization mass spectrometry (2015) Sci. Justice, , (in press) Balko, L., Allison, J., The direct detection and identification of staining dyes from security inks in the presence of other colorants, on currency and fabrics, by laser desorption mass spectrometry (2003) J. Forensic Sci., 48, pp. 1172-1178 Weston, D.J., Ambient ionization mass spectrometry: current understanding of mechanistic theory analytical performance and application areas (2010) Analyst, 135, pp. 661-668 Harris, G.A., Nyadong, L., Fernandez, F.M., Recent developments in ambient ionization techniques for analytical mass spectrometry (2008) Analyst, 133, pp. 1297-1301 Ifa, D.R., Wu, C., Ouyang, Z., Cooks, R.G., Desorption electrospray ionization and other ambient ionization methods: current progress and preview (2010) Analyst, 135, pp. 669-681 Takáts, Z., Wiseman, J.M., Gologan, B., Cooks, R.G., Mass spectrometry sampling under ambient conditions with desorption electrospray ionization (2004) Science, 306, pp. 471-473 Cody, R.B., Laramée, J.A., Durst, H.D., Versatile new ion source for the analysis of materials in open air under ambient conditions (2005) Anal. Chem., 77, pp. 2297-2302 Shiea, J., Huang, M.Z., Hsu, H.J., Lee, C.Y., Yuan, C.H., Beech, I., Electrospray-assisted laser desorption/ionization mass spectrometry for direct ambient analysis of solids (2005) Rapid Commun. Mass Spectrom., 19, pp. 3701-3704 Zhu, L., Gamez, G., Chen, H., Chingin, K., Zenobi, R., Rapid detection of melamine in untreated milk and wheat gluten by ultrasound-assisted extractive electrospray ionization mass spectrometry (EESI-MS) (2009) Chem. Commun., 55, pp. 9-61 Haapala, M., Pól, J., Saarela, V., Arvola, V., Kotiaho, T., Ketola, R.A., Desorption atmospheric pressure photoionization (2007) Anal. Chem., 79, pp. 7867-7872 Haddad, R., Sparrapan, R., Eberlin, M.N., Desorption sonic spray ionization for (high) voltage-free ambient mass spectrometry (2006) Rapid Commun. Mass Spectrom., 20, pp. 2901-2905 Alberici, R.M., Simas, R.C., Sanvido, G.B., Romão, W., Lalli, P.M., Benassi, M., Ambient mass spectrometry: bringing MS into the real world (2010) Anal. Bioanal. Chem., 398, pp. 265-294 Ifa, D.R., Jackson, A.U., Paglia, G., Cooks, R.G., Forensic applications of ambient ionization mass spectrometry (2009) Anal. Bioanal. Chem., 394, pp. 1995-2008 Pfaff, A.M., Steiner, R.R., Development and validation of AccuTOF-DART™ as a screening method for analysis of bank security device and pepper spray components (2011) Forensic Sci. Int., 206, pp. 62-70 Wu, C., Dill, A.L., Eberlin, L.S., Cooks, R.G., Ifa, D.R., Mass spectrometry imaging under ambient conditions (2013) Mass Spectrom. Rev., 32, pp. 218-243 Ifa, D.R., Wiseman, J.M., Song, Q., Cooks, R.G., Development of capabilities for imaging mass spectrometry under ambient conditions with desorption electrospray ionization (DESI) (2007) Int. J. Mass Spectrom., 259, pp. 8-15 Ifa, D.R., Gumaelius, L.M., Eberlin, L.S., Manicke, N.E., Cooks, R.G., Forensic analysis of inks by imaging desorption electrospray ionization (DESI) mass spectrometry (2007) Analyst, 132, pp. 461-467 Ifa, D.R., Manicke, N.E., Dill, A.L., Cooks, R.G., Latent fingerprint chemical imaging by mass spectrometry (2008) Science, 321, p. 805 Forbes, T.P., Sisco, E., Chemical imaging of artificial fingerprints by desorption electro-flow focusing ionization mass spectrometry (2014) Analyst, 139, pp. 2982-2985