Artículos de revistas
Crystal Structure Of 7-[(2e)-2-benzyl-idene-3-oxobut-oxy]-4-methyl-2h-chromen-2-one.
Registro en:
Acta Crystallographica. Section E, Crystallographic Communications. v. 71, n. Pt 4, p. o222-223, 2015-Apr.
2056-9890
10.1107/S2056989015003084
26029424
Autor
Caracelli, Ignez
Zukerman-Schpector, Julio
Moran, Paulo J S
de Paula, Bruno R S
Tiekink, Edward R T
Institución
Resumen
Two independent mol-ecules (A and B) comprise the asymmetric unit of the title compound, C21H18O4. There are significant conformational differences between the mol-ecules relating in particular to the relative orientation of the 3-oxo-2-(phenyl-methyl-idene)but-oxy substituent with respect to the superimposable chromen-2-one residues. To a first approximation, the substituents are mirror images; both are approximately perpendicular to the chromen-2-one fused ring system with dihedral angles of 88.50 (7) (A) and 81.96 (7)° (B). Another difference between the independent mol-ecules is noted in the dihedral angles between the adjacent phenyl and but-3-en-2-one groups of 8.72 (12) (A) and 27.70 (10)° (B). The conformation about the ethene bond in both mol-ecules is E. The crystal packing features C-H⋯O, C-H⋯π(ar-yl) and π-π [Cg⋯Cg = 3.6657 (8) and 3.7778 (8) Å] stacking inter-actions, which generate a three-dimensional network. 71 o222-223