Artículos de revistas
Total Synthesis And Tentative Structural Elucidation Of Cryptomoscatone E3: Interplay Of Experimental And Computational Studies.
Registro en:
The Journal Of Organic Chemistry. v. 80, n. 24, p. 12027-12037, 2015-Dec.
1520-6904
10.1021/acs.joc.5b01956
26513545
Autor
Novaes, Luiz F T
Sarotti, Ariel M
Pilli, Ronaldo A
Institución
Resumen
A successful combination of computational chemistry and total synthesis was explored to tentatively elucidate the absolute configuration of cryptomoscatone E3, a polyketide isolated from the Brazilian tree Cryptocarya mandiocanna. Two independent synthetic approaches are discussed based on asymmetric allylation, ring closing metathesis, and aldol reactions. 80 12027-12037