Artículos de revistas
Dba-free" Palladium Intermediates Of The Heck-matsuda Reaction."
Registro en:
Organic & Biomolecular Chemistry. v. 11, n. 20, p. 3277-81, 2013-May.
1477-0539
10.1039/c3ob40142a
23511838
Autor
Machado, Angelo H L
Milagre, Humberto M S
Eberlin, Livia S
Sabino, Adão A
Correia, Carlos Roque D
Eberlin, Marcos N
Institución
Resumen
The dba-free Heck-Matsuda reaction was investigated via direct ESI-MS(/MS) monitoring. Palladium species involved in the reduction of Pd(II) during a Wacker type reaction and several dba-free arylpalladium transient complexes were detected and characterized. Based on these findings, a more comprehensible catalytic cycle for this pivotal reaction is suggested. 11 3277-81