Artículos de revistas
Total Synthesis Of (-)-goniotrionin.
Registro en:
The Journal Of Organic Chemistry. v. 77, n. 8, p. 4046-62, 2012-Apr.
1520-6904
10.1021/jo3004106
22443275
Autor
Dias, Luiz C
Ferreira, Marco A B
Institución
Resumen
A stereoselective total synthesis of the reported structure of goniotrionin (4) has been accomplished. The key steps involved the opening of a chiral epoxide, a highly diastereoselective Mukaiyama aerobic oxidative cyclization, a selective 1,2-syn Mukaiyama aldol reaction, and a Noyori reduction. 77 4046-62