Artículos de revistas
Microwave-immobilized Polybutadiene Stationary Phase For Reversed-phase High-performance Liquid Chromatography.
Journal Of Chromatography. A. v. 1030, n. 1-2, p. 225-9, 2004-Mar.
Lopes, Nilva P
Collins, Kenneth E
Jardim, Isabel C S F
Polybutadiene (PBD) has been immobilized on high-performance liquid chromatography (HPLC) silica by microwave radiation at various power levels (52-663 W) and actuation times (3-60 min). Columns prepared from these reversed-phase HPLC materials, as well as from similar non-irradiated materials, were tested with standard sample mixtures and characterized by elemental analysis (%C) and infrared spectroscopy. A microwave irradiation of 20 min at 663 W gives a layer of immobilized PBD that presented good performance. Longer irradiation times give thicker immobilized layers having less favorable chromatographic properties.1030225-9