Artículos de revistas
A STUDY OF THE THERMAL-BEHAVIOR OF ALPHA-LAYERED TIN(IV) PHOSPHONATE SN(C3H5O2PO3)(2)
Registro en:
Thermochimica Acta. Elsevier Science Bv, v. 241, n. 33, n. 41, 1994.
0040-6031
WOS:A1994PG20100004
10.1016/0040-6031(94)87004-7
Autor
MEDEIROS, ME
ALVES, OL
Institución
Resumen
The thermal behaviour of tin(IV) 2-carboxyethylphosphonate was studied by TGA and DSC techniques under oxygen and nitrogen atmospheres. The decomposition stages are more defined in nitrogen than in oxygen, but in both cases the layered compound is stable up to around 300 degrees C. Samples treated thermally at temperatures ranging from 100 to 900 degrees C for 1 h at atmospheric pressure exhibit XRD and FTIR data suggesting the formation of Sn(HPO4)(2) as intermediate and the cubic pyrophosphate as the final product of the decomposition. 241 33 41