Artículos de revistas
Organofunctionalized Amazon smectite for dye removal from aqueous medium-Kinetic and thermodynamic adsorption investigations
Registro en:
Journal Of Hazardous Materials. Elsevier Science Bv, v. 186, n. 1, n. 675, n. 682, 2011.
0304-3894
WOS:000288102400085
10.1016/j.jhazmat.2010.11.054
Autor
Guerra, DL
Silva, WLL
Oliveira, HCP
Viana, RR
Airoldi, C
Institución
Resumen
Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq) Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP) The objective of this study is to examine the adsorption behavior of Sumifix Brilliant Orange 3R textile dye from aqueous solution on smectite sample, an abundant Amazon clay. The original smectite clay mineral has been collected from Amazon region, Brazil. The compound 2-aminomethylpyridine was anchored onto smectite surface by heterogeneous route. The ability of these materials to remove the Sumifix Brilliant Orange 3R textile dye from aqueous solution was followed by a series of adsorption isotherms, using a batchwise process. The maximum number of moles adsorbed was determined to be 1.26 and 2.07 mmol g(-1) for natural and modified clay samples, respectively. The energetic effects caused by dye cations adsorption were determined through calorimetric titrations. Thermodynamics indicated the existence of favorable conditions for such dye-nitrogen interactions. (C) 2010 Published by Elsevier B.V. 186 1 675 682 Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq) Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP) Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq) Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)