Artículos de revistas
Enantioselective synthesis of alpha-hydroxysilanes by bioreduction of aroyltrimethylsilanes
Registro en:
Journal Of The Chemical Society-perkin Transactions 1. Royal Soc Chemistry, n. 21, n. 3133, n. 3137, 1999.
0300-922X
WOS:000085587900015
10.1039/a906335h
Autor
Patrocinio, AF
Correa, IR
Moran, PJS
Institución
Resumen
Aromatic acylsilanes [Ar-CO-SiMe3; Ar = C6H5, 4-ClC6H4, 2-, 3- and 4-OMeC6H4, 3,4-(OMe)(2)C6H5 and 3,4-OCH2OC6H3] were reduced by baker's yeast to optically active alpha-silyl alcohols in 20-70% yield and 43-88% ee. Comments are made on the influence of silicon in this bioreduction reaction. 21 3133 3137