dc.creatorDallmann, K
dc.creatorBuffon, R
dc.creatorLoh, W
dc.date2002
dc.date44927
dc.date2014-11-14T09:32:17Z
dc.date2015-11-26T17:14:14Z
dc.date2014-11-14T09:32:17Z
dc.date2015-11-26T17:14:14Z
dc.date.accessioned2018-03-29T00:02:34Z
dc.date.available2018-03-29T00:02:34Z
dc.identifierJournal Of Molecular Catalysis A-chemical. Elsevier Science Bv, v. 178, n. 41671, n. 43, n. 46, 2002.
dc.identifier1381-1169
dc.identifierWOS:000173274500006
dc.identifier10.1016/S1381-1169(01)00293-X
dc.identifierhttp://www.repositorio.unicamp.br/jspui/handle/REPOSIP/78499
dc.identifierhttp://www.repositorio.unicamp.br/handle/REPOSIP/78499
dc.identifierhttp://repositorio.unicamp.br/jspui/handle/REPOSIP/78499
dc.identifier.urihttp://repositorioslatinoamericanos.uchile.cl/handle/2250/1281765
dc.descriptionAddition of poly(ethylene oxide) (PEO) to the catalytic system MoO2(acac)(2)/TBHP/t-butanol used for epoxidation of olefins allowed an easy strategy for catalyst recycling and product recovery. This procedure is based upon catalyst removal by precipitation of a complex with the polymer, being advantageous over other similar recycling methodologies in that there is no requirement for specially prepared catalysts or solvents. Although some catalyst leaching is detected, the epoxidation of cis-cyclooctene was achieved with global turnover numbers close to 650. (C) 2002 Elsevier Science B.V. All rights reserved.
dc.description178
dc.description41671
dc.description43
dc.description46
dc.languageen
dc.publisherElsevier Science Bv
dc.publisherAmsterdam
dc.publisherHolanda
dc.relationJournal Of Molecular Catalysis A-chemical
dc.relationJ. Mol. Catal. A-Chem.
dc.rightsfechado
dc.rightshttp://www.elsevier.com/about/open-access/open-access-policies/article-posting-policy
dc.sourceWeb of Science
dc.subjectolefin epoxidation
dc.subjectcatalyst recycling
dc.subjectpolymer-bound complexes
dc.subjectTert-butyl Hydroperoxide
dc.subjectImidazole-containing Polymers
dc.subjectCyclohexene
dc.subjectComplexes
dc.subjectOlefins
dc.subjectSystems
dc.subjectMo(vi)
dc.subjectMo
dc.titleCatalyst recycling in the epoxidation of alkenes catalyzed by MoO2(acac)(2) through precipitation with poly(ethylene oxide)
dc.typeArtículos de revistas


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