Artículos de revistas
HYDRIDE TRANSFER VERSUS ELECTRON-TRANSFER IN THE BAKERS-YEAST REDUCTION OF ALPHA-HALOACETOPHENONES
Registro en:
Bioorganic & Medicinal Chemistry Letters. Pergamon-elsevier Science Ltd, v. 3, n. 8, n. 1637, n. 1642, 1993.
0960-894X
WOS:A1993LW59200031
10.1016/S0960-894X(00)80033-5
Autor
ALEIXO, LM
DECARVALHO, M
MORAN, PJS
RODRIGUES, JAR
Institución
Resumen
The baker's yeast reduction of alpha-iodoacetophenone gave acetophenone. Some evidence for a free radical chain process in this reduction was obtained by addition of DNB which not only provoked a decrease in the formation of acetophenone but also allow the appearance of the enzyme-controlled formation of (-)-(R)-2-iodo-1-phenylethanol. 3 8 1637 1642