Artículos de revistas
Direct conversion of acylsilanes to esters mediated by iron (III) and nitrate ions
Registro en:
Synthetic Communications. Marcel Dekker Inc, v. 30, n. 8, n. 1419, n. 1423, 2000.
0039-7911
WOS:000086376200009
10.1080/00397910008087169
Autor
Patrocinio, AF
Moran, PJS
Institución
Resumen
Acylsilanes, RC(O)SiMe3 (R = C6H5, p-MeOC6H4 and C5H11), can be converted into their corresponding carboxylic acids, when water is used as solvent, and esters when alcohol is used as solvent. This oxidation is mediated by iron (III) ions in 20-24 h or nitric acid diluted in alcohol in 2-10 h at room temperature. 30 8 1419 1423