Artículos de revistas
Addition of carbon nucleophiles to substituted N-acyliminium ions. A stereoselective route to trans-fused decahydroquinoline systems
Registro en:
Tetrahedron Letters. Pergamon-elsevier Science Ltd, v. 41, n. 41, n. 7843, n. 7846, 2000.
0040-4039
WOS:000089809800012
10.1016/S0040-4039(00)01362-9
Autor
Maldaner, AO
Pilli, RA
Institución
Resumen
A stereoselective route to trans-fused 2-substituted decahydroquinoline hydrochloride 11 featuring the addition of allyl tri-n-butyltin to a disubstituted N-acyliminium ion derived from glutarimide, followed by ring-closing metathesis is described (seven steps, 13% overall yield from lactam 4). (C) 2000 Elsevier Science Ltd. All rights reserved. 41 41 7843 7846