Artículos de revistas
Total synthesis of (-)-decarestrictine D through a stereoselective intramolecular Nozaki-Hiyama-Kishi reaction
Registro en:
Tetrahedron Letters. Pergamon-elsevier Science Ltd, v. 39, n. 25, n. 4421, n. 4424, 1998.
0040-4039
WOS:000074032900005
10.1016/S0040-4039(98)00837-5
Autor
Pilli, RA
Victor, MM
Institución
Resumen
A concise total synthesis of (-)-decarestrictine D (1) from 1,3-propanediol and polyhydroxybutyrate (PHB) is described. The approach involves the stereoselective intramolecular Nozaki-Hiyama-Kishi coupling to construct the decanolide ring and to set the proper configuration at C-7. (C) 1998 Published by Elsevier Science Ltd. All rights reserved. 39 25 4421 4424