Palladium(II) complex with S-allyl-L-cysteine: New solid-state NMR spectroscopic measurements, molecular modeling and antibacterial assays

dc.creatorSpera, MBM
dc.creatorQuintao, FA
dc.creatorFerraresi, DKD
dc.creatorLustri, WR
dc.creatorMagalhaes, A
dc.creatorFormiga, ALB
dc.creatorCorbi, PP
dc.date2011
dc.dateJAN
dc.date2014-07-30T14:30:36Z
dc.date2015-11-26T16:41:09Z
dc.date2014-07-30T14:30:36Z
dc.date2015-11-26T16:41:09Z
dc.date.accessioned2018-03-28T23:25:17Z
dc.date.available2018-03-28T23:25:17Z
dc.identifierSpectrochimica Acta Part A-molecular And Biomolecular Spectroscopy. Pergamon-elsevier Science Ltd, v. 78, n. 1, n. 313, n. 318, 2011.
dc.identifier1386-1425
dc.identifierWOS:000287107000048
dc.identifier10.1016/j.saa.2010.10.012
dc.identifierhttp://www.repositorio.unicamp.br/jspui/handle/REPOSIP/59002
dc.identifierhttp://repositorio.unicamp.br/jspui/handle/REPOSIP/59002
dc.identifier.urihttp://repositorioslatinoamericanos.uchile.cl/handle/2250/1272839
dc.descriptionConselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)
dc.descriptionFundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)
dc.descriptionNuclear magnetic resonance studies, molecular modeling and antibacterial assays of the palladium(II) complex with S-allyl-L-cysteine (deoxyalliin) are presented. Studies based on solid and solution (13)C and (15)N nuclear magnetic resonance (NMR) spectroscopy confirmed that the palladium(II) complex preserved the same structural arrangement in both states, with no modifications on coordination sphere when dissolved in water. Density functional theory (DFT) studies stated that the trans isomer is the most stable one. Antibacterial activities of S-allyl-L-cysteine and its palladium(II) complex were evaluated by antibiogram assays using the disc diffusion method. The palladium(II) complex showed an effective antibacterial activity against Staphylococcus aureus (Gram-positive), Escherichia coli and Pseudomonas aeruginosa (Gram-negative) bacterial cells. (C) 2010 Elsevier B.V. All rights reserved.
dc.description78
dc.description1
dc.description313
dc.description318
dc.descriptionFAEPEX
dc.descriptionConselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)
dc.descriptionFundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)
dc.descriptionConselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)
dc.descriptionFundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)
dc.descriptionCNPq [479415-2009-9]
dc.descriptionFAPESP [2006/55367-2]
dc.languageen
dc.publisherPergamon-elsevier Science Ltd
dc.publisherOxford
dc.publisherInglaterra
dc.relationSpectrochimica Acta Part A-molecular And Biomolecular Spectroscopy
dc.relationSpectroc. Acta Pt. A-Molec. Biomolec. Spectr.
dc.rightsfechado
dc.rightshttp://www.elsevier.com/about/open-access/open-access-policies/article-posting-policy
dc.sourceWeb of Science
dc.subjectS-Allyl-L-cysteine
dc.subjectPalladium(II)
dc.subjectSolid-state (15)N NMR
dc.subjectMolecular modeling
dc.subjectAntibacterial agents
dc.subjectGaussian-type Basis
dc.subjectOrbital Methods
dc.subjectOrganic-molecules
dc.subjectCrystal-structure
dc.subjectPlatinum(ii)
dc.subjectDeoxyalliin
dc.subjectDerivatives
dc.subjectChemistry
dc.subjectDensity
dc.subjectPt(ii)
dc.titlePalladium(II) complex with S-allyl-L-cysteine: New solid-state NMR spectroscopic measurements, molecular modeling and antibacterial assays
dc.typeArtículos de revistas


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