Artículos de revistas
The asymmetric synthesis of (+)-sitophilure, the natural form of the aggregation pheromone of Sitophilus oryzae L-and Sitophilus zeamais M.
Registro en:
Journal Of The Brazilian Chemical Society. Soc Brasileira Quimica, v. 10, n. 5, n. 363, n. 368, 1999.
0103-5053
WOS:000084012100005
Autor
Pilli, RA
Riatto, VB
Institución
Resumen
The asymmetric synthesis of (+)-sitophilure, the aggregation pheromone of Sitophilus oryzae L,. and Sitophilus zeamais M., was carried out in 12 steps, 18% overall yield and 82% enantiomeric excess from the enzymatic reduction of methyl 3-oxopentanoate with S. cerevisiae in the presence of ethyl chloroacetate. 10 5 363 368