Artículos de revistas
Reduction of Hexavalent Chromium in Soil and Ground Water Using Zero-Valent Iron Under Batch and Semi-Batch Conditions
Registro en:
Water Air And Soil Pollution. Springer, v. 197, n. 41730, n. 49, n. 60, 2009.
0049-6979
WOS:000262551000006
10.1007/s11270-008-9790-0
Autor
Franco, DV
Da Silva, LM
Jardim, WF
Institución
Resumen
Chemical remediation of soil and groundwater containing hexavalent chromium (Cr(VI)) was carried out under batch and semi-batch conditions using different iron species: (Fe(II) (sulphate solution); Fe(0) (G) (granulated elemental iron); ZVIne (non-stabilized zerovalent iron) and ZVIcol (colloidal zerovalent iron). ZVIcol was synthesized using different experimental conditions with carboxymethyl cellulose (CMC) and ultra-sound. Chemical analysis revealed that the contaminated soil (frank clay sandy texture) presented an average Cr(VI) concentration of 456 +/- 35 mg kg(-1). Remediation studies carried out under batch conditions indicated that 1.00 g of ZVIcol leads to a chemical reduction of similar to 280 mg of Cr(VI). Considering the fractions of Cr(VI) present in soil (labile, exchangeable and insoluble), it was noted that after treatment with ZVIcol (semi-batch conditions and pH 5) only 2.5% of these species were not reduced. A comparative study using iron species was carried out in order to evaluate the reduction potentialities exhibited by ZVIcol. Results obtained under batch and semi-batch conditions indicate that application of ZVIcol for the 'in situ' remediation of soil and groundwater containing Cr(VI) constitutes a promising technology. 197 41730 49 60